Hmm i dont think this is possible.
But why do you want to map the LAN adress 192.168.0.221 to 10.0.0.50?
from within the external LAN you can access the 10.0.0.50 without any problem.
PS: there is a very dirty way that you should only use if you realy need it and it only works if the servers inside your network dont need acces to the IP addresses from the vendors net:
you could assing the webserver for example the 192.168.0.221 and in monowall add a static route:
iface: LAN
destination: 192.168.0.221
gateway: 10.0.0.5
yes, this is a very dirty and ugly way
