Just so I am clear, you want only a single computer to access that printer? if that is the case then in rules on the LAN interface setup with the "not" option on the source, that will block all computers on the LAN from the printer except the one defined in the rule.
As an example if this is the IP of the PC 192.168.1.5 and this was the IP of the printer 192.168.1.10 your rule should look like this
Proto Source Port Destination Port Description (Reject) TCP/UDP ! 192.168.1.5 * 192.168.1.10 * check printer (Pass) * LAN net * * * Default Lan -> any
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