If the old ISP uses DHCP (ie cable modem) it could be possible to hack this in using manual NATing and firing up a DHCP client on the OPT interface you're using for that ISP. (using exec.php)
For PPPoE however it would be more complicated. You'd have to create another config file, fire up a virtual interface etcpp, make m0n0wall aware of it etcpp. I wouldn't even try then.
